This study probes the chemical abundances of the neutron-capture elements cerium and neodymium in the inner Milky Way from an analysis of a sample of similar to 2000 stars in the Galactic bulge bar spatially contained within divided by X-Gal divided by < 5 kpc, divided by Y-Gal divided by < 3.5 kpc, and divided by Z(Gal)divided by < 1 kpc, and spanning metallicities between -2.0 less than or similar to [Fe/H] less than or similar to +0.5. We classify the sample stars into low- or high-[Mg/Fe] populations and find that, in general, values of [Ce/Fe] and [Nd/Fe] increase as the metallicity decreases for the low- and high-[Mg/Fe] populations. Ce abundances show a more complex variation across the metallicity range of our bulge-bar sample when compared to Nd, with the r-process dominating the production of neutron-capture elements in the high-[Mg/Fe] population ([Ce/Nd] < 0.0). We find a spatial chemical dependence of Ce and Nd abundances for our sample of bulge-bar stars, with low- and high-[Mg/Fe] populations displaying a distinct abundance distribution. In the region close to the center of the MW, the low-[Mg/Fe] population is dominated by stars with low [Ce/Fe], [Ce/Mg], [Nd/Mg], [Nd/Fe], and [Ce/Nd] ratios. The low [Ce/Nd] ratio indicates a significant contribution in this central region from r-process yields for the low-[Mg/Fe] population. The chemical pattern of the most metal-poor stars in our sample suggests an early chemical enrichment of the bulge dominated by yields from core-collapse supernovae and r-process astrophysical sites, such as magnetorotational supernovae.

Context. Carbon abundances in first-ascent giant stars are usually lower than those of their main-sequence counterparts. At moderate metallicities, stellar evolution of single stars cannot account for the existence of red-giant branch stars with enhanced carbon abundances. The phenomenon is usually interpreted as resulting from past mass transfer from an evolved binary companion now in the white dwarf evolutionary stage.

Aims. We aim to confirm the links between [C/O] enhancement, s-process element enhancement and binary fraction using large-scale catalogues of stellar abundances and probable binary stars.

Methods. We use a large data set from the 17^th data release of the SDSS-IV/APOGEE 2 survey to identify carbon-enhanced stars in the Galactic disk. We identify a continuum of carbon enrichment throughout three different sub-populations of disk stars and explore links between the degree of carbon enrichment and binary frequency, metallicity and chemical compositions.

Results. We verify a clear correlation between binary frequency and enhancement in the abundances of both carbon and cerium, lending support to the scenario whereby carbon-enhanced stars are the result of mass transfer by an evolved binary companion. In addition, we identify clustering in the carbon abundances of high-α disk stars, suggesting that those on the high metallicity end are likely younger, in agreement with theoretical predictions for the presence of a starburst population following the gas-rich merger of the Gaia-Enceladus/Sausage system.

The relative enrichment of s-process to α-elements ([s/α]) has been linked with age, providing a potentially useful avenue in exploring the Milky Way’s chemical evolution. However, the age–[s/α] relationship is non-universal, with dependencies on metallicity and current location in the Galaxy. In this work, we examine these chemical clock tracers across birth radii (⁠𝑅birth⁠), recovering the inherent trends between the variables. We derive 𝑅birth and explore the [s/α]–age–𝑅birth relationship for 36 652 APOGEE DR17 red giant and 24 467 GALAH DR3 main-sequence turn-off and subgiant branch disc stars using [Ce/Mg], [Ba/Mg], and [Y/Mg]. We discover that the age–[𝑠/Mg] relation is strongly dependent on birth location in the Milky Way, with stars born in the inner disc having the weakest correlation. This is congruent with the Galaxy’s initially weak, negative [𝑠/Mg] radial gradient, which becomes positive and steep with time. We show that the non-universal relations of chemical clocks is caused by their fundamental trends with 𝑅birth over time, and suggest that the tight age–[𝑠/Mg] relation obtained with solar-like stars is due to similar 𝑅birth for a given age. Our results are put into context with a Galactic chemical evolution model, where we demonstrate the need for data-driven nucleosynthetic yields.

Context. Open clusters are ideal tools for tracing the abundances of different elements because their stars are expected to have the same age, distance, and metallicity. Therefore, they serve as powerful tracers for investigating the cosmic origins of elements. This paper expands on a recent study by us, in which the element fluorine was studied in seven open clusters; here we add six open clusters and eight field stars.

Aims. The primary objective is to determine the abundance of fluorine (F) to gain insight into its production and evolution. The magnesium (Mg) abundances were derived to categorize the field stars into high and low alpha disk populations. Additionally, cerium (Ce) abundances were determined to better understand the interplay between F and s-process elements. Our goal is to analyze the trend of F abundances across the Galactic disk based on metallicity and age. By comparing observational data with Galactic chemical evolution models, the origin of F can be better understood.

Methods. The spectra were obtained from the high-resolution near-infrared GIANO-B instrument at the Telescopio Nazionale Galileo (TNG). For the derivation of the stellar parameters and abundances, the Python version of Spectroscopy Made Easy (PySME) was used. OH, CN, and CO molecular lines and band heads along with Fe I lines were used to determine the stellar parameters in the H-band region. Two HF lines in the K band (λλ 2.28, and 2.33 μm), three K-band Mg I lines (λλ 2.10, 2.11, and 2.15 μm), and two Ce II lines in the H band (λλ 1.66, and 1.71 μm) were used to derive the abundances of F, Mg, and Ce, respectively.

Results. F, Mg, and Ce abundances were derived for 14 stars from 6 OCs, as well as for 8 field stars. The F and Ce abundances were investigated as a function of metallicity, age, and galactocentric distance. We also compared our findings with different Galactic chemical evolution models.

Conclusions. Our results indicate that asymptotic giant branch stars and massive stars, including a subset of fast rotators (whose rotation speed likely increases as metallicity decreases), are necessary to explain the cosmic origin of F. This finding is consistent with and, with the large sample size, reinforces the conclusion of our previous study.

Context. To be able to investigate the chemical history of the entire Milky Way, it is imperative to also study its dust-obscured regions in detail, as this is where most of the mass lies. The Galactic Center is an example of such a region. Due to the intervening dust along the line of sight, near-infrared spectroscopic investigations are necessary to study this region of interest. Aims. The aim of this work is to demonstrate that M giants observed at high spectral resolution in the H- and K-bands (1.5-2.4 mu m) can yield useful abundance ratio trends versus metallicity for 21 elements. These elements can then also be studied for heavily dust-obscured regions of the Galaxy, such as the Galactic Center. The abundance ratio trends will be important for further investigation of the Galactic chemical evolution in these regions. Methods. We observed near-infrared spectra of 50 M giants in the solar neighborhood at high signal-to-noise and at a high spectral resolution with the IGRINS spectrometer on the Gemini South telescope. The full H- and K-bands were recorded simultaneously at R = 45 000. Using a manual spectral synthesis method, we determined the fundamental stellar parameters for these stars and derived the stellar abundances for 21 atomic elements, namely, F, Mg, Si, S, Ca, Na, Al, K, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Y, Ce, Nd, and Yb. We systematically studied useful spectral lines of all these elements in the H- and K-bands. Results. We demonstrate that elements can be analyzed from H- and K-band high-resolution spectra, and we show which spectral lines can be used for an abundance analysis, identifying them line by line. We discuss the 21 abundance ratio trends and compare them with those determined from APOGEE and from the optical Giants in the Local Disk (GILD) sample. From high-resolution H- and K-band spectra, the trends of the heavy elements Cu, Zn, Y, Ce, Nd, and Yb can be retrieved. This opens up the nucleosynthetic channels, including the s-process and the r-process in dust-obscured populations. The [Mn/Fe] versus [Fe/H] trend is shown to be more or less flat at low metallicities, implying that existing non-local thermodynamic equilibrium correction is relevant. Conclusions. With high-resolution near-infrared spectra, it is possible to determine reliable abundance ratio trends versus metallicity for 21 elements, including elements formed in several different nucleosynthetic channels. It is also possible to determine the important neutron-capture elements, both s- and r-dominated elements. This opens up the possibility to study the chemical evolution in detail of dust-obscured regions of the Milky Way, such as the Galactic Center. The M giants are useful bright probes for these regions and for future studies of extra-galactic stellar populations. A careful analysis of high-quality spectra is needed to retrieve all of these elements, which are often from weak and blended lines. A spectral resolution of R greater than or similar to 40 000 is a further quality that helps in deriving precise abundances for this range of elements. In comparison to APOGEE, we can readily obtain the abundances for Cu, Ce, Nd, and Yb from the H-band, demonstrating an advantage of analyzing high-resolution spectra.

Context. The age, evolution, and chemical properties of the Galactic disk can be effectively ascertained using open clusters. Within the large program Stellar Populations Astrophysics at the Telescopio Nazionale Galileo, we specifically focused on stars in open clusters, to investigate various astrophysical topics, from the chemical content of very young systems to the abundance patterns of lesser studied intermediate-age and old open clusters.

Aims. We investigate the astrophysically interesting element fluorine (F), which has an uncertain and intriguing cosmic origin. We also determine the abundance of cerium (Ce), as F abundance is expected to correlate with the s-process elements. We intend to determine the trend of F abundance across the Galactic disk as a function of metallicity and age. This will offer insights into Galactic chemical evolution models, potentially enhancing our comprehension of this element’s cosmic origin.

Methods. High-resolution near-infrared spectra were obtained using the GIANO-B spectrograph. The Python version of Spectroscopy Made Easy (PySME), was used to derive atmospheric parameters and abundances. The stellar parameters were determined using OH, CN, and CO molecular lines along with Fe I lines. The F and Ce abundances were inferred using two K-band HF lines (λλ 2.28, 2.33 µm) and two atomic H-band lines (λλ 1.66, and 1.71 µm), respectively.

Results. Of all the clusters in our sample, only King 11 had not been previously studied through medium- to high-resolution spectroscopy, and our stellar parameter and metallicity findings align well with those documented in the literature. We have successfully inferred F and Ce abundances in all seven open clusters and probed the radial and age distributions of abundance ratios. This paper presents the first F Galactic radial abundance gradient. Our results are also compared with literature estimates and with Galactic chemical evolution models that have been generated using different F production channels.

Conclusions. Our results indicate a constant, solar pattern in the [F/Fe] ratios across clusters of different ages, supporting the latest findings that fluorine levels do not exhibit any secondary behavior for stars with solar or above-solar metallicity. However, an exception to this trend is seen in NGC 6791, a metal-rich, ancient cluster whose chemical composition is distinct due to its enhanced fluorine abundance. This anomaly strengthens the hypothesis that NGC 6791 originated in the inner regions of the Galaxy before migrating to its present position. By comparing our sample stars with the predictions of Galactic chemical evolution models, we came to the conclusion that both asymptotic giant branch stars and massive stars, including a fraction of fast rotators that increase with decreasing metallicity, are needed to explain the cosmic origin of F.

We introduce the Sloan Digital Sky Survey (SDSS)/ Apache Point Observatory Galactic Evolution Experiment (APOGEE) value-added catalogue of Galactic globular cluster (GC) stars. The catalogue is the result of a critical search of the APOGEE Data Release 17 (DR17) catalogue for candidate members of all known Galactic GCs. Candidate members are assigned to various GCs on the basis of position in the sky, proper motion, and radial velocity. The catalogue contains a total of 7737 entries for 6422 unique stars associated with 72 Galactic GCs. Full APOGEE DR17 information is provided, including radial velocities and abundances for up to 20 elements. Membership probabilities estimated on the basis of precision radial velocities are made available. Comparisons with chemical compositions derived from the GALactic Archaeology with HERMES (GALAH) survey, as well as optical values from the literature, show good agreement. This catalogue represents a significant increase in the public data base of GC star chemical compositions and kinematics, providing a massive homogeneous data set that will enable a variety of studies. The catalogue in fits format is available for public download from the SDSS-IV DR17 value-added catalogue website.

We present a catalog of fundamental stellar properties for similar to 7500 evolved stars, including stellar radii and masses, determined from the combination of spectroscopic observations from the Apache Point Observatory Galactic Evolution Experiment, part of the Sloan Digital Sky Survey IV, and asteroseismology from K2. The resulting APO-K2 catalog provides spectroscopically derived temperatures and metallicities, asteroseismic global parameters, evolutionary states, and asteroseismically derived masses and radii. Additionally, we include kinematic information from Gaia. We investigate the multidimensional space of abundance, stellar mass, and velocity with an eye toward applications in Galactic archaeology. The APO-K2 sample has a large population of low-metallicity stars (similar to 288 with [M/H] <= -1), and their asteroseismic masses are larger than astrophysical estimates. We argue that this may reflect offsets in the adopted fundamental temperature scale for metal-poor stars rather than metallicity-dependent issues with interpreting asteroseismic data. We characterize the kinematic properties of the population as a function of alpha enhancement and position in the disk and identify those stars in the sample that are candidate components of the Gaia-Enceladus merger. Importantly, we characterize the selection function for the APO-K2 sample as a function of metallicity, radius, mass, nu max , color, and magnitude referencing Galactic simulations and target selection criteria to enable robust statistical inferences with the catalog.

We use data from the 17th data release of the Apache Point Observatory Galactic Evolution Experiment (APOGEE 2) to contrast the chemical composition of the recently discovered Gaia Enceladus/Sausage system (GE/S) to those of 10 Milky Way (MW) dwarf satellite galaxies: LMC, SMC, Boötes I, Carina, Draco, Fornax, Sagittarius, Sculptor, Sextans, and Ursa Minor. Our main focus is on the distributions of the stellar populations of those systems in the [Mg/Fe]–[Fe/H] and [Mg/Mn]–[Al/Fe] planes, which are commonly employed in the literature for chemical diagnosis and where dwarf galaxies can be distinguished from in situ populations. We show that, unlike MW satellites, a GE/S sample defined purely on the basis of orbital parameters falls almost entirely within the locus of ‘accreted’ stellar populations in chemical space, which is likely caused by an early quenching of star formation in GE/S. Due to a more protracted history of star formation, stars in the metal-rich end of the MW satellite populations are characterized by lower [Mg/Mn] than those of their GE/S counterparts. The chemical compositions of GE/S stars are consistent with a higher early star formation rate (SFR) than MW satellites of comparable and even higher mass, suggesting that star formation in the early universe was strongly influenced by other parameters in addition to mass. We find that the direction of the metallicity gradient in the [Mg/Mn]–[Al/Fe] plane of dwarf galaxies is an indicator of the early SFR of the system. 

We present new maps of the Milky Way disk showing the distribution of metallicity ([Fe/H]), alpha-element abundances ([Mg/Fe]), and stellar age, using a sample of 66,496 red giant stars from the final data release (DR17) of the Apache Point Observatory Galactic Evolution Experiment survey. We measure radial and vertical gradients, quantify the distribution functions for age and metallicity, and explore chemical clock relations across the Milky Way for the low-a disk, high-alpha disk, and total population independently. The low-alpha disk exhibits a negative radial metallicity gradient of -0.06 +/- 0.001 dex kpc(-1), which flattens with distance from the midplane. The high-alpha disk shows a flat radial gradient in metallicity and age across nearly all locations of the disk. The age and metallicity distribution functions shift from negatively skewed in the inner Galaxy to positively skewed at large radius. Significant bimodality in the [Mg/Fe]-[Fe/H] plane and in the [Mg/Fe]-age relation persist across the entire disk. The age estimates have typical uncertainties of similar to 0.15 in log(age) and may be subject to additional systematic errors, which impose limitations on conclusions drawn from this sample. Nevertheless, these results act as critical constraints on galactic evolution models, constraining which physical processes played a dominant role in the formation of the Milky Way disk. We discuss how radial migration predicts many of the observed trends near the solar neighborhood and in the outer disk, but an additional more dramatic evolution history, such as the multi-infall model or a merger event, is needed to explain the chemical and age bimodality elsewhere in the Galaxy.

Previous results in the literature have found the young inner-disc open cluster NGC 6705 to be mildly alpha-enhanced. We examined this possibility via an independent chemical abundance analysis for 11 red-giant members of NGC 6705. The analysis is based on near-infrared APOGEE spectra and relies on LTE calculations using spherical model atmospheres and radiative transfer. We find a mean cluster metallicity of [Fe / H] = +0.13 +/- 0.04, indicating that NGC 6705 is metal-rich, as may be expected for a young inner-disc cluster. The mean alpha-element abundance relative to iron is , which is not at odds with expectations from general Galactic abundance trends. NGC 6705 also provides important probes for studying stellar mixing, given its turn-off mass of M similar to 3.3M(circle dot). Its red giants have low C-12 abundances ([C-12/Fe] = -0.16) and enhanced N-14 abundances ([N-14/Fe] = +0.51), which are key signatures of the first dredge-up on the red giant branch. An additional signature of dredge-up was found in the Na abundances, which are enhanced by [Na/Fe] = +0.29, with a very small non-LTE correction. The O-16 and Al abundances are found to be near-solar. All of the derived mixing-sensitive abundances are in agreement with stellar models of approximately 3.3M(circle dot) evolving along the red giant branch and onto the red clump. As found in young open clusters with similar metallicities, NGC 6705 exhibits a mild excess in the s-process element cerium with [Ce/Fe] = +0.13 +/- 0.07.

Aims. Stars with strong enhancements of r-process elements are rare and tend to be metal-poor, generally with [Fe/H] < -2 dex, and located in the halo. In this work, we aim to investigate a candidate r-process enriched bulge star with a relatively high metallicity of [Fe/H] similar to - 0.65 dex and to compare it with a previously published r-rich candidate star in the bulge. Methods. We reconsidered the abundance analysis of a high-resolution optical spectrum of the red-giant star 2MASS J18082459-2548444 and determined its europium (Eu) and molybdenum (Mo) abundance, using stellar parameters from five different previous studies. Applying 2MASS photometry, Gaia astrometry, and kinematics, we estimated the distance, orbits, and population membership of 2MASS J18082459-2548444 and a previously reported r-enriched star 2MASS J18174532-3353235. Results. We find that 2MASS J18082459-2548444 is a relatively metal-rich, enriched r-process star that is enhanced in Eu and Mo, but not substantially enhanced in s-process elements. There is a high probability that it has a Galactic bulge membership, based on its distance and orbit. We find that both stars show r-process enhancement with elevated [Eu/Fe]-values, even though 2MASS J18174532-3353235 is 1 dex lower in metallicity. Additionally, we find that the plausible origins of 2MASS J18174532-3353235 to be either that of the halo or the thick disc. Conclusions. We conclude that 2MASS J18082459-2548444 represents the first example of a confirmed r-process enhanced star confined to the inner bulge. We assume it is possibly a relic from a period of enrichment associated with the formation of the bar.

Context. Classical Cepheids (CCs) are solid distance indicators and tracers of young stellar populations. Dating back to the beginning of the 20th century, they have been safely adopted to trace the rotation, kinematics, and chemical enrichment history of the Galactic thin disk.

Aims. The main aim of this investigation is to provide iron, oxygen, and sulfur abundances for the largest and most homogeneous sample of Galactic CCs analyzed so far (1118 spectra of 356 objects). The current sample, containing 70 CCs for which spectroscopic metal abundances are provided for the first time, covers a wide range in galactocentric distances, pulsation modes, and pulsation periods.

Methods. Optical high-resolution spectra with a high signal-to-noise ratio that were collected with different spectrographs were adopted to provide homogeneous estimates of the atmospheric parameters (effective temperature, surface gravity, and microturbulent velocity) that are required to determine the abundance. Individual distances were based either on trigonometric parallaxes by the Gaia Data Release 3 (Gaia DR3) or on distances based on near-infrared period-luminosity relations.

Results. We found that iron and α-element radial gradients based on CCs display a well-defined change in the slope for galactocentric distances larger than ~12 kpc. We also found that logarithmic regressions account for the variation in [X/H] abundances from the inner to the outer disk. Radial gradients for the same elements, but based on open clusters covering a wide range in cluster ages, display similar trends. This means that the flattening in the outer disk is an intrinsic feature of the radial gradients because it is independent of age. Empirical evidence indicates that the S radial gradient is steeper than the Fe radial gradient. The difference in the slope is a factor of two in the linear fit (−0.081 vs. −0.041 dex kpc−1) and changes from −1.62 to −0.91 in the logarithmic distance. Moreover, we found that S (explosive nucleosynthesis) is underabundant on average when compared with O (hydrostatic nucleosynthesis). The difference becomes clearer in the metal-poor regime and for the [O/Fe] and [S/Fe] abundance ratios. We performed a detailed comparison with Galactic chemical evolution models and found that a constant star formation efficiency for galactocentric distances larger than 12 kpc accounts for the flattening observed in both iron and α-elements. To further constrain the impact of the predicted S yields for massive stars on radial gradients, we adopted a toy model and found that the flattening in the outermost regions requires a decrease of a factor of four in the current S predictions.

Conclusions. CCs are solid beacons for tracing the recent chemical enrichment of young stellar populations. Sulfur photospheric abundances, when compared with other α-elements, have the key advantage of being a volatile element. Therefore, stellar S abundances can be directly compared with nebular sulfur abundances in external galaxies.

We present a spectroscopic analysis of a sample of 48 M-dwarf stars (0.2 M (& ODOT;) < M < 0.6 M (& ODOT;)) from the Hyades open cluster using high-resolution H-band spectra from the Sloan Digital Sky Survey/Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey. Our methodology adopts spectrum synthesis with LTE MARCS model atmospheres, along with the APOGEE Data Release 17 line list, to determine effective temperatures, surface gravities, metallicities, and projected rotational velocities. The median metallicity obtained for the Hyades M dwarfs is [M/H] = 0.09 & PLUSMN; 0.03 dex, indicating a small internal uncertainty and good agreement with optical results for Hyades red giants. Overall, the median radii are larger than predicted by stellar models by 1.6% & PLUSMN; 2.3% and 2.4% & PLUSMN; 2.3%, relative to a MIST and DARTMOUTH isochrone, respectively. We emphasize, however, that these isochrones are different, and the fractional radius inflation for the fully and partially convective regimes have distinct behaviors depending on the isochrone. Using a MIST isochrone there is no evidence of radius inflation for the fully convective stars, while for the partially convective M dwarfs the radii are inflated by 2.7% & PLUSMN; 2.1%, which is in agreement with predictions from models that include magnetic fields. For the partially convective stars, rapid rotators present on average higher inflation levels than slow rotators. The comparison with SPOTS isochrone models indicates that the derived M-dwarf radii can be explained by accounting for stellar spots in the photosphere of the stars, with 76% of the studied M dwarfs having up to 20% spot coverage, and the most inflated stars with & SIM;20%-40% spot coverage.

Galactic haloes in a ?-CDM universe are predicted to host today a swarm of debris resulting from cannibalized dwarf galaxies. The chemodynamical information recorded in their stellar populations helps elucidate their nature, constraining the assembly history of the Galaxy. Using data from APOGEE and Gaia, we examine the chemical properties of various halo substructures, considering elements that sample various nucleosynthetic pathways. The systems studied are Heracles, Gaia-Enceladus/Sausage (GES), the Helmi stream, Sequoia, Thamnos, Aleph, LMS-1, Arjuna, I'itoi, Nyx, Icarus, and Pontus. Abundance patterns of all substructures are cross-compared in a statistically robust fashion. Our main findings include: (i) the chemical properties of most substructures studied match qualitatively those of dwarf Milky Way satellites, such as the Sagittarius dSph. Exceptions are Nyx and Aleph, which are chemically similar to disc stars, implying that these substructures were likely formed in situ; (ii) Heracles differs chemically from in situ populations such as Aurora and its inner halo counterparts in a statistically significant way. The differences suggest that the star formation rate was lower in Heracles than in the early Milky Way; (iii) the chemistry of Arjuna, LMS-1, and I'itoi is indistinguishable from that of GES, suggesting a possible common origin; (iv) all three Sequoia samples studied are qualitatively similar. However, only two of those samples present chemistry that is consistent with GES in a statistically significant fashion; (v) the abundance patterns of the Helmi stream and Thamnos are different from all other halo substructures.

Abundance gradients are one of the few observables constraining the chemo-dynamical models of the Milky Way disk. Here, we review recent improvements regarding the determination of chemical abundances of young stellar systems, Cepheids, and RGB stars, that are used to trace abundance gradients, before focusing on the oxygen gradient.

Aims. In this work, we aim to make a differential comparison of the neutron-capture and p-process element molybdenum (Mo) in the stellar populations in the local disk(s) and the bulge, focusing on minimising possible systematic effects in the analysis. Methods. The stellar sample consists of 45 bulge and 291 local disk K-giants observed with high-resolution optical spectra. The abundances are determined by fitting synthetic spectra using the Spectroscopy Made Easy (SME) code. The disk sample is separated into thin and thick disk components using a combination of abundances and kinematics. The cosmic origin of Mo is investigated and discussed by comparing with published abundances of Mo and the neutron-capture elements cerium (Ce) and europium (Eu). Results. We determine reliable Mo abundances for 35 bulge and 282 disk giants with a typical uncertainty of [Mo/Fe] similar to 0.2 and similar to 0.1 dex for the bulge and disk, respectively. Conclusions. We find that the bulge is possibly enhanced in [Mo/Fe] compared to the thick disk, which we do not observe in either [Ce/Fe] or [Eu/Fe]. This might suggest a higher past star-formation rate in the bulge; however, as we do not observe the bulge to be enhanced in [Eu/Fe], the origin of the molybdenum enhancement is yet to be constrained. Although the scatter is large, we may be observing evidence of the p-process contributing to the heavy element production in the chemical evolution of the bulge.

Recent results from chemical tagging studies using Apache Point Observatory Galactic Evolution Experiment data suggest a strong link between the chemical abundance patterns of stars found within globular clusters (GC), and chemically peculiar populations in the Galactic halo field. In this paper, we analyse the chemical compositions of stars within the cluster body and tidal streams of Palomar 5, a GC that is being tidally disrupted by interaction with the Galactic gravitational potential. We report the identification of nitrogen-rich (N-rich) stars both within and beyond the tidal radius of Palomar 5, with the latter being clearly aligned with the cluster tidal streams; this acts as confirmation that N-rich stars are lost to the Galactic halo from GCs, and provides support to the hypothesis that field N-rich stars identified by various groups have a GC origin.

Elements with weak and blended spectral features in stellar spectra are challenging to measure and require specialized analysis methods to precisely measure their chemical abundances. In this work, we have created a catalog of approximately 120,000 giants with high signal-to-noise Apache Point Observatory Galactic Evolution Experiment (APOGEE) Data Release 17 (DR17) spectra, for which we explore weak and blended species to measure Na, P, S, V, Cu, Ce, and Nd abundances and C-12/C-13 isotopic ratios. We employ an updated version of the Brussels Automatic Code for Characterizing High-accuracy Spectra (BACCHUS) code to derive these abundances using the stellar parameters measured by APOGEE's DR17 Stellar Parameters and Chemical Abundances Pipeline, quality flagging to identify suspect spectral lines, and a prescription for upper limits. Combined, these allow us to provide our BACCHUS Analysis of Weak Lines in APOGEE Spectra catalog of precise chemical abundances for these weak and blended species, which agrees well with the literature and improves upon APOGEE abundances for these elements, some of which are unable to be measured with APOGEE's current, grid-based approach without computationally expensive expansions. This new catalog can be used alongside APOGEE and provides measurements for many scientific applications ranging from nuclear physics to Galactic chemical evolution and Milky Way population studies. To illustrate this we show some examples of uses for this catalog, such as showing that we observe stars with enhanced s-process abundances or that we can use the C-12/C-13 ratios to explore extra mixing along the red giant branch.

We apply a novel statistical analysis to measurements of 16 elemental abundances in 34,410 Milky Way disk stars from the final data release (DR17) of APOGEE-2. Building on recent work, we fit median abundance ratio trends [X/Mg] versus [Mg/H] with a 2-process model, which decomposes abundance patterns into a "prompt" component tracing core-collapse supernovae and a "delayed" component tracing Type Ia supernovae. For each sample star, we fit the amplitudes of these two components, then compute the residuals Delta[X/H] from this two-parameter fit. The rms residuals range from similar to 0.01-0.03 dex for the most precisely measured APOGEE abundances to similar to 0.1 dex for Na, V, and Ce. The correlations of residuals reveal a complex underlying structure, including a correlated element group comprised of Ca, Na, Al, K, Cr, and Ce and a separate group comprised of Ni, V, Mn, and Co. Selecting stars poorly fit by the 2-process model reveals a rich variety of physical outliers and sometimes subtle measurement errors. Residual abundances allow for the comparison of populations controlled for differences in metallicity and [alpha/Fe]. Relative to the main disk (R = 3-13 kpc), we find nearly identical abundance patterns in the outer disk (R = 15-17 kpc), 0.05-0.2 dex depressions of multiple elements in LMC and Gaia Sausage/Enceladus stars, and wild deviations (0.4-1 dex) of multiple elements in omega Cen. The residual abundance analysis opens new opportunities for discovering chemically distinctive stars and stellar populations, for empirically constraining nucleosynthetic yields, and for testing chemical evolution models that include stochasticity in the production and redistribution of elements.

Context. Measuring the abundances of neutron-capture elements in Galactic disk stars is an important part of understanding key stellar and galactic processes. In the optical wavelength regime a number of different neutron-capture elements have been measured; however, only the s-process-dominated element cerium has been accurately measured for a large sample of disk stars from the infrared H band. The more r-process dominated element ytterbium has only been measured in a small subset of stars so far. Aims. In this study we aim to measure the ytterbium (Yb) abundance of local disk giants using the Yb II line at lambda(air) = 16 498 angstrom. We also compare the resulting abundance trend with cerium and europium abundances for the same stars to analyse the s- and r-process contributions. Methods. We analyse 30 K giants with high-resolution H band spectra using spectral synthesis. The very same stars have already been analysed using high-resolution optical spectra via the same method, but it was not possible to determine the abundance of Yb from those spectra due to blending issues for stars with [Fe/H] > -1. In the present analysis, we utilise the stellar parameters determined from the optical analysis. Results. We determined the Yb abundances with an estimated uncertainty for [Yb/Fe] of 0.1 dex. By comparison, we found that the [Yb/Fe] trend closely follows the [Eu/Fe] trend and has clear s-process enrichment in identified s-rich stars. This comparison confirms both that the validity of the Yb abundances is ensured and that the theoretical prediction that the s-/r-process contribution to the origin of Yb of roughly 40/60 is supported. Conclusions. These results show that, with a careful and detailed analysis of infrared spectra, reliable Yb abundances can be derived for a wider sample of cooler giants in the range -1.1 < [Fe/H] < 0.3. This is promising for further studies of the production of Yb and for the r-process channel, key for galactochemical evolution, in the infrared.

Individual chemical abundances for 14 elements (C, O, Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, and Ni) are derived for a sample of M dwarfs using high-resolution, near-infrared H-band spectra from the Sloan Digital Sky Survey-IV/Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey. The quantitative analysis included synthetic spectra computed with 1D LTE plane-parallel MARCS models using the APOGEE Data Release 17 line list to determine chemical abundances. The sample consists of 11 M dwarfs in binary systems with warmer FGK dwarf primaries and 10 measured interferometric angular diameters. To minimize atomic diffusion effects, [X/Fe] ratios are used to compare M dwarfs in binary systems and literature results for their warmer primary stars, indicating good agreement (<0.08 dex) for all studied elements. The mean abundance difference in primaries minus this work's M dwarfs is -0.05 +/- 0.03 dex. It indicates that M dwarfs in binary systems are a reliable way to calibrate empirical relationships. A comparison with abundance, effective temperature, and surface gravity results from the APOGEE Stellar Parameter and Chemical Abundances Pipeline (ASPCAP) Data Release 16 finds a systematic offset of [M/H], T (eff), log g = +0.21 dex, -50 K, and 0.30 dex, respectively, although ASPCAP [X/Fe] ratios are generally consistent with this study. The metallicities of the M dwarfs cover the range of [Fe/H] = -0.9 to +0.4 and are used to investigate Galactic chemical evolution via trends of [X/Fe] as a function of [Fe/H]. The behavior of the various elemental abundances [X/Fe] versus [Fe/H] agrees well with the corresponding trends derived from warmer FGK dwarfs, demonstrating that the APOGEE spectra can be used to examine Galactic chemical evolution using large samples of selected M dwarfs.

The APOGEE Open Cluster Chemical Abundances and Mapping survey is used to probe the chemical evolution of the s-process element cerium in the Galactic disk. Cerium abundances were derived from measurements of Ce ii lines in the APOGEE spectra using the Brussels Automatic Code for Characterizing High Accuracy Spectra in 218 stars belonging to 42 open clusters. Our results indicate that, in general, for ages < 4 Gyr, younger open clusters have higher [Ce/Fe] and [Ce/α-element] ratios than older clusters. In addition, metallicity segregates open clusters in the [Ce/X]–age plane (where X can be H, Fe, or the α-elements O, Mg, Si, or Ca). These metallicity-dependent relations result in [Ce/Fe] and [Ce/α] ratios with ages that are not universal clocks. Radial gradients of [Ce/H] and [Ce/Fe] ratios in open clusters, binned by age, were derived for the first time, with d[Ce/H]/dRGC being negative, while d[Ce/Fe]/dRGC is positive. [Ce/H] and [Ce/Fe] gradients are approximately constant over time, with the [Ce/Fe] gradient becoming slightly steeper, changing by ∼+0.009 dex kpc−1 Gyr−1. Both the [Ce/H] and [Ce/Fe] gradients are shifted to lower values of [Ce/H] and [Ce/Fe] for older open clusters. The chemical pattern of Ce in open clusters across the Galactic disk is discussed within the context of s-process yields from asymptotic giant branch (AGB) stars, gigayear time delays in Ce enrichment of the interstellar medium, and the strong dependence of Ce nucleosynthesis on the metallicity of its AGB stellar sources.

Context. In the last 15 years different ground-based spectroscopic surveys have been started (and completed) with the general aim of delivering stellar parameters and elemental abundances for large samples of Galactic stars, complementing Gaia astrometry. Among those surveys, the Gaia-ESO Public Spectroscopic Survey, the only one performed on a 8m class telescope, was designed to target 100 000 stars using FLAMES on the ESO VLT (both Giraffe and UVES spectrographs), covering all the Milky Way populations, with a special focus on open star clusters. Aims. This article provides an overview of the survey implementation (observations, data quality, analysis and its success, data products, and releases), of the open cluster survey, of the science results and potential, and of the survey legacy. A companion article reviews the overall survey motivation, strategy, Giraffe pipeline data reduction, organisation, and workflow. Methods. We made use of the information recorded and archived in the observing blocks; during the observing runs; in a number of relevant documents; in the spectra and master catalogue of spectra; in the parameters delivered by the analysis nodes and the working groups; in the final catalogue; and in the science papers. Based on these sources, we critically analyse and discuss the output and products of the Survey, including science highlights. We also determined the average metallicities of the open clusters observed as science targets and of a sample of clusters whose spectra were retrieved from the ESO archive. Results. The Gaia-ESO Survey has determined homogeneous good-quality radial velocities and stellar parameters for a large fraction of its more than 110 000 unique target stars. Elemental abundances were derived for up to 31 elements for targets observed with UVES. Lithium abundances are delivered for about 1/3 of the sample. The analysis and homogenisation strategies have proven to be successful; several science topics have been addressed by the Gaia-ESO consortium and the community, with many highlight results achieved. Conclusions. The final catalogue will be released through the ESO archive in the first half of 2022, including the complete set of advanced data products. In addition to these results, the Gaia-ESO Survey will leave a very important legacy, for several aspects and for many years to come.

Context. The Gaia-ESO Public Spectroscopic Survey is an ambitious project designed to obtain astrophysical parameters and elemental abundances for 100 000 stars, including large representative samples of the stellar populations in the Galaxy, and a well-defined sample of 60 (plus 20 archive) open clusters. We provide internally consistent results calibrated on benchmark stars and star clusters, extending across a very wide range of abundances and ages. This provides a legacy data set of intrinsic value, and equally a large wide-ranging dataset that is of value for the homogenisation of other and future stellar surveys and Gaia's astrophysical parameters. Aims. This article provides an overview of the survey methodology, the scientific aims, and the implementation, including a description of the data processing for the GIRAFFE spectra. A companion paper introduces the survey results. Methods. Gaia-ESO aspires to quantify both random and systematic contributions to measurement uncertainties. Thus, all available spectroscopic analysis techniques are utilised, each spectrum being analysed by up to several different analysis pipelines, with considerable effort being made to homogenise and calibrate the resulting parameters. We describe here the sequence of activities up to delivery of processed data products to the ESO Science Archive Facility for open use. Results. The Gaia-ESO Survey obtained 202 000 spectra of 115 000 stars using 340 allocated VLT nights between December 2011 and January 2018 from GIRAFFE and UVES. Conclusions. The full consistently reduced final data set of spectra was released through the ESO Science Archive Facility in late 2020, with the full astrophysical parameters sets following in 2022. A companion article reviews the survey implementation, scientific highlights, the open cluster survey, and data products.

Context. Phosphorus (P) is considered to be one of the key elements for life, making it an important element to look for in the abundance analysis of spectra of stellar systems. Yet, only a select number of spectroscopic studies exist to estimate the phosphorus abundances and investigate its trend across a range of metallicities. This is due to the lack of good phosphorus lines in the optical wavelength region and the requirement of careful manual analysis of the blended phosphorus lines in near-infrared H-band spectra obtained with individual observations and surveys such as the Apache Point Observatory Galactic Evolution Experiment (APOGEE). Aims. Based on a consistent and systematic analysis of high-resolution, near-infrared Immersion GRating INfrared Spectrograph (IGRINS) spectra of 38 K giant stars in the Solar neighborhood, we present and investigate the phosphorus abundance trend in the metallicity range of -1.2 dex < [Fe/H] < 0.4 dex. Furthermore, we compare this trend with the available chemical evolution models to shed some light on the origin and evolution of phosphorus. Methods. We have observed full H- and K-band spectra at a spectral resolving power of R = 45 000 with IGRINS mounted on the Gemini South telescope, the Discovery Channel Telescope, and the Harlan J Smith Telescope at McDonald Observatory. Abundances were determined from spectral lines by modeling the synthetic spectrum that best matches the observed spectrum by chi(2) minimization. For this task, we used the Spectroscopy Made Easy (SME) tool in combination with one-dimensional (1D) Model Atmospheres in a Radiative and Convective Scheme (MARCS) stellar atmosphere models. The investigated sample of stars have reliable stellar parameters estimated using optical FIber-fed Echelle Spectrograph (FIES) spectra obtained in a previous study of a set of stars called Giants in the Local Disk (GILD). In order to determine the phosphorus abundances from the 16482.92 angstrom phosphorus line, we needed to take special care blending the CO(v = 7-4) line. With the stellar parameters known, we thus determined the C, N, and O abundances from atomic carbon and a range of nonblended molecular lines (CO, CN, and OH) which are plentiful in the H-band region of K giant stars, assuring an appropriate modeling of the blending CO(v = 7-4) line. Results. We present the [P/Fe] versus [Fe/H] trend for K giant stars in the metallicity range of -1.2 dex < [Fe/H] < 0.4 dex and enhanced phosphorus abundances for two metal-poor s-rich stars. We find that our trend matches well with the compiled literature sample of prominently dwarf stars and the limited number of giant stars. Our trend is found to be higher by similar to 0.05-0.1 dex compared to the theoretical chemical evolution trend resulting from the core collapse supernova (type II) of massive stars with the phosphorus yields arbitrarily increased by a factor of 2.75. Thus the enhancement factor might need to be similar to 0.05-0.1 dex higher to match our trend. We also find an empirically determined primary behavior for phosphorus. Furthermore, the phosphorus abundance is found to be elevated by similar to 0.6-0.9 dex in the two s-enriched stars compared to the theoretical chemical evolution trend.

The chemical abundances of planet-hosting stars offer a glimpse into the composition of planet-forming environments. To further understand this connection, we make the first ever measurement of the correlation between planet occurrence and chemical abundances for ten different elements (C, Mg, Al, Si, S, K, Ca, Mn, Fe, and Ni). Leveraging data from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) and Gaia to derive precise stellar parameters (sigma(R star) approximate to 2.3%, sigma(M star) approximate to 4.5%) for a sample of 1018 Kepler Objects of Interest, we construct a sample of well-vetted Kepler planets with precisely measured radii (sigma(Rp) approximate to 3.4%). After controlling for biases in the Kepler detection pipeline and the selection function of the APOGEE survey, we characterize the relationship between planet occurrence and chemical abundance as the number density of nuclei of each element in a star's photosphere raised to a power, beta. varies by planet type, but is consistent within our uncertainties across all ten elements. For hot planets (P = 1-10 days), an enhancement in any element of 0.1 dex corresponds to an increased occurrence of approximate to 20% for super-Earths (R-p = 1-1.9 R-circle plus) and approximate to 60% for sub-Neptunes (R-p = 1.9-4 R-circle plus). Trends are weaker for warm (P = 10-100 days) planets of all sizes and for all elements, with the potential exception of sub-Saturns (R-p = 4-8 R.). Finally, we conclude this work with a caution to interpreting trends between planet occurrence and stellar age due to degeneracies caused by Galactic chemical evolution and make predictions for planet occurrence rates in nearby open clusters to facilitate demographics studies of young planetary systems.

The goal of the Open Cluster Chemical Abundances and Mapping (OCCAM) survey is to constrain key Galactic dynamic and chemical evolution parameters by the construction and analysis of a large, comprehensive, uniform data set of infrared spectra for stars in hundreds of open clusters. This sixth contribution from the OCCAM survey presents analysis of SDSS/APOGEE Data Release 17 (DR17) results for a sample of stars in 150 open clusters, 94 of which we designate to be "high-quality" based on the appearance of their color-magnitude diagram. We find the APOGEE DR17-derived [Fe/H] values to be in good agreement with those from previous high-resolution spectroscopic open cluster abundance studies. Using a subset of the high-quality sample, the Galactic abundance gradients were measured for 16 chemical elements, including [Fe/H], for both Galactocentric radius (R (GC)) and guiding center radius (R (guide)). We find an overall Galactic [Fe/H] versus R (GC) gradient of -0.073 +/- 0.002 dex kpc(-1) over the range of 6 > R (GC) < 11.5 kpc, and a similar gradient is found for [Fe/H] versus R (guide). Significant Galactic abundance gradients are also noted for O, Mg, S, Ca, Mn, Na, Al, K, and Ce. Our large sample additionally allows us to explore the evolution of the gradients in four age bins for the remaining 15 elements.

Large-scale surveys open the possibility to investigate Galactic evolution both chemically and kinematically; however, reliable stellar ages remain a major challenge. Detailed chemical information provided by high-resolution spectroscopic surveys of the stars in clusters can be used as a means to calibrate recently developed chemical tools for age-dating field stars. Using data from the Open Cluster Abundances and Mapping survey, based on the Sloan Digital Sky Survey/Apache Point Observatory Galactic Evolution Experiment 2 survey, we derive a new empirical relationship between open cluster stellar ages and the carbon-to-nitrogen ([C/N]) abundance ratios for evolved stars, primarily those on the red giant branch. With this calibration, [C/N] can be used as a chemical clock for evolved field stars to investigate the formation and evolution of different parts of our Galaxy. We explore how mixing effects at different stellar evolutionary phases, like the red clump, affect the derived calibration. We have established the [C/N]-age calibration for APOGEE Data Release 17 (DR17) giant star abundances to be log [Age(yr)](DR17) = 10.14 (+/- 0.08) + 2.23(+/- 0.19) [C/N], usable for 8.62 <= log(Age[yr]) <= 9.82, derived from a uniform sample of 49 clusters observed as part of APOGEE DR17 applicable primarily to metal-rich, thin- and thick-disk giant stars. This measured [C/N]-age APOGEE DR17 calibration is also shown to be consistent with asteroseismic ages derived from Kepler photometry.

This paper documents the seventeenth data release (DR17) from the Sloan Digital Sky Surveys; the fifth and final release from the fourth phase (SDSS-IV). DR17 contains the complete release of the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey, which reached its goal of surveying over 10,000 nearby galaxies. The complete release of the MaNGA Stellar Library accompanies this data, providing observations of almost 30,000 stars through the MaNGA instrument during bright time. DR17 also contains the complete release of the Apache Point Observatory Galactic Evolution Experiment 2 survey that publicly releases infrared spectra of over 650,000 stars. The main sample from the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), as well as the subsurvey Time Domain Spectroscopic Survey data were fully released in DR16. New single-fiber optical spectroscopy released in DR17 is from the SPectroscipic IDentification of ERosita Survey subsurvey and the eBOSS-RM program. Along with the primary data sets, DR17 includes 25 new or updated value-added catalogs. This paper concludes the release of SDSS-IV survey data. SDSS continues into its fifth phase with observations already underway for the Milky Way Mapper, Local Volume Mapper, and Black Hole Mapper surveys.

The SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey has obtained high-resolution spectra for thousands of red giant stars distributed among the massive satellite galaxies of the Milky Way (MW): the Large and Small Magellanic Clouds (LMC/SMC), the Sagittarius Dwarf Galaxy (Sgr), Fornax (Fnx), and the now fully disrupted Gaia Sausage/Enceladus (GSE) system. We present and analyze the APOGEE chemical abundance patterns of each galaxy to draw robust conclusions about their star formation histories, by quantifying the relative abundance trends of multiple elements (C, N, O, Mg, Al, Si, Ca, Fe, Ni, and Ce), as well as by fitting chemical evolution models to the [alpha/Fe]-[Fe/H] abundance plane for each galaxy. Results show that the chemical signatures of the starburst in the Magellanic Clouds (MCs) observed by Nidever et al. in the alpha-element abundances extend to C+N, Al, and Ni, with the major burst in the SMC occurring some 3-4 Gyr before the burst in the LMC. We find that Sgr and Fnx also exhibit chemical abundance patterns suggestive of secondary star formation epochs, but these events were weaker and earlier (similar to 5-7 Gyr ago) than those observed in the MCs. There is no chemical evidence of a second starburst in GSE, but this galaxy shows the strongest initial star formation as compared to the other four galaxies. All dwarf galaxies had greater relative contributions of AGB stars to their enrichment than the MW. Comparing and contrasting these chemical patterns highlight the importance of galaxy environment on its chemical evolution.

Context. We describe the atomic and molecular data that were used for the abundance analyses of FGK-type stars carried out within the Gaia-ESO Public Spectroscopic Survey in the years 2012 to 2019. The Gaia-ESO Survey is one among several current and future stellar spectroscopic surveys producing abundances for Milky-Way stars on an industrial scale.Aims. We present an unprecedented effort to create a homogeneous common line list, which was used by several abundance analysis groups using different radiative transfer codes to calculate synthetic spectra and equivalent widths. The atomic data are accompanied by quality indicators and detailed references to the sources. The atomic and molecular data are made publicly available at the CDS.Methods. In general, experimental transition probabilities were preferred but theoretical values were also used. Astrophysical gf-values were avoided due to the model-dependence of such a procedure. For elements whose lines are significantly affected by a hyperfine structure or isotopic splitting, a concerted effort has been made to collate the necessary data for the individual line components. Synthetic stellar spectra calculated for the Sun and Arcturus were used to assess the blending properties of the lines. We also performed adetailed investigation of available data for line broadening due to collisions with neutral hydrogen atoms.Results. Among a subset of over 1300 lines of 35 elements in the wavelength ranges from 475 to 685 nm and from 850 to 895 nm, we identified about 200 lines of 24 species which have accurate gf-values and are free of blends in the spectra of the Sun and Arcturus. For the broadening due to collisions with neutral hydrogen, we recommend data based on Anstee-Barklem-O'Mara theory, where possible. We recommend avoiding lines of neutral species for which these are not available. Theoretical broadening data by R.L. Kurucz should be used for ScII, TiII, and YII lines; additionally, for ionised rare-earth species, the Unsold approximation with an enhancement factor of 1.5 for the line width can be used.Conclusions. The line list has proven to be a useful tool for abundance determinations based on the spectra obtained within the Gaia-ESO Survey, as well as other spectroscopic projects. Accuracies below 0.2 dex are regularly achieved, where part of the uncertainties are due to differences in the employed analysis methods. Desirable improvements in atomic data were identified for a number of species, most importantly AlI, SI, and CrII, but also NaI, SiI, CaII, and NiI.

Context. Bulge globular clusters (BGCs) are exceptional tracers of the formation and chemodynamical evolution of this oldest Galactic component. However, until now, observational difficulties have prevented us from taking full advantage of these powerful Galactic archeological tools. Aims. CAPOS, the bulge Cluster APOgee Survey, addresses this key topic by observing a large number of BGCs, most of which have only been poorly studied previously. Even their most basic parameters, such as metallicity, [alpha/Fe], and radial velocity, are generally very uncertain. We aim to obtain accurate mean values for these parameters, as well as abundances for a number of other elements, and explore multiple populations. In this first paper, we describe the CAPOS project and present initial results for seven BGCs. Methods. CAPOS uses the APOGEE-2S spectrograph observing in the H band to penetrate obscuring dust toward the bulge. For this initial paper, we use abundances derived from ASPCAP, the APOGEE pipeline. Results. We derive mean [Fe/H] values of -0.85 +/- 0.04 (Terzan 2), -1.40 +/- 0.05 (Terzan 4), -1.20 +/- 0.10 (HP 1), -1.40 +/- 0.07 (Terzan 9), -1.07 +/- 0.09 (Djorg 2), -1.06 +/- 0.06 (NGC 6540), and -1.11 +/- 0.04 (NGC 6642) from three to ten stars per cluster. We determine mean abundances for eleven other elements plus the mean [alpha/Fe] and radial velocity. CAPOS clusters significantly increase the sample of well-studied Main Bulge globular clusters (GCs) and also extend them to lower metallicity. We reinforce the finding that Main Bulge and Main Disk GCs, formed in situ, have [Si/Fe] abundances slightly higher than their accreted counterparts at the same metallicity. We investigate multiple populations and find our clusters generally follow the light-element (anti)correlation trends of previous studies of GCs of similar metallicity. We finally explore the abundances of the iron-peak elements Mn and Ni and compare their trends with field populations. Conclusions. CAPOS is proving to be an unprecedented resource for greatly improving our knowledge of the formation and evolution of BGCs and the bulge itself.

We study the multiple populations of omega Cen by using the abundances of Fe, C, N, O, Mg, Al, Si, K, Ca, and Ce from the high-resolution, high signal-to-noise (S/N > 70) spectra of 982 red giant stars observed by the SDSS-IV/APOGEE-2 survey. We find that the shape of the Al-Mg and N-C anticorrelations changes as a function of metallicity, continuous for the metal-poor groups, but bimodal (or unimodal) at high metallicities. There are four Fe populations, similarly to previous literature findings, but we find seven populations based on Fe, Al, and Mg abundances. The evolution of Al in omega Cen is compared to its evolution in the Milky Way and in five representative globular clusters. We find that the distribution of Al in metal-rich stars of omega Cen closely follows what is observed in the Galaxy. Other alpha-elements and C, N, O, and Ce are also compared to the Milky Way, and significantly elevated abundances are observed over what is found in the thick disc for almost all elements. However, we also find some stars with high metallicity and low [Al/Fe], suggesting that omega Cen could be the remnant core of a dwarf galaxy, but the existence of these peculiar stars needs an independent confirmation. We also confirm the increase in the sum of CNO as a function of metallicity previously reported in the literature and find that the [C/N] ratio appears to show opposite correlations between Al-poor and Al-rich stars as a function of metallicity.

The standard picture of galaxy formation motivates the decomposition of the Milky Way into 3-4 stellar populations with distinct kinematic and elemental abundance distributions: the thin disk, thick disk, bulge, and stellar halo. To test this idea, we construct a Gaussian mixture model (GMM) for both simulated and observed stars in the solar neighborhood, using measured velocities and iron abundances (i.e., an augmented Toomre diagram) as the distributions to be decomposed. We compare results for the Gaia-APOGEE DR16 crossmatch catalog of the solar neighborhood with those from a suite of synthetic Gaia-APOGEE crossmatches constructed from FIRE-2 cosmological simulations of Milky Way mass galaxies. We find that in both the synthetic and real data, the best-fit GMM uses five independent components, some of whose properties resemble the standard populations predicted by galaxy formation theory. Two components can be identified unambiguously as the thin disk and another as the halo. However, instead of a single counterpart to the thick disk, there are three intermediate components with different age and alpha abundance distributions (although these data are not used to construct the model). We use decompositions of the synthetic data to show that the classified components indeed correspond to stars with different origins. By analogy with the simulated data, we show that our mixture model of the real Gaia-APOGEE crossmatch distinguishes the following components: (1) a classic thin disk of young stars on circular orbits (46%), (2) thin disk stars heated by interactions with satellites (22%), (3, 4) two components representing the velocity asymmetry of the alpha-enhanced thick disk (27%), and (5) a stellar halo consistent with early, massive accretion (4%).