The Galactic center and inner disk of the Milky Way contain complex stellar populations obscured by heavy dust extinction. To study their chemical composition, high-resolution near-infrared (near-IR) spectroscopy is necessary. Expanding the set of elements measurable in the near-IR, especially neutron-capture elements, improves our ability to trace nucleosynthesis and Galactic chemical evolution. This work aims to identify and characterize a spectral line suitable for determining rubidium (Rb) abundances. Rubidium is produced in roughly equal parts by the r- and s-processes. We analyze high-resolution (R = 45,000) Immersion GRating INfrared Spectrograph (or IGRINS) near-IR spectra of 40 M giants in the solar neighborhood, most observed with Gemini South. We perform spectral synthesis of the Rb i line at 15289.48 Å, using new log g f values and including an astrophysical calibration of the blending Fe i lines. The resulting [Rb/Fe] ratios are compared to other neutron-capture elements and interpreted with chemical evolution models. We demonstrate that the used Rb line is a reliable abundance indicator in M giants and the coolest K giants, but becomes too weak at higher temperatures. [Rb/Fe] shows a decreasing trend with metallicity, mirroring that of ytterbium (Yb), another mixed r-/s-process element. Our results agree with optical studies, validating the use of this near-IR line. Comparisons with chemical evolution models confirm that both s- and r-process sources are needed to explain the Rb trend. This work adds Rb to the list of elements measurable in high-resolution H- and K-band spectra, enabling studies of one more neutron-capture element in dust-obscured regions like the Galactic center and inner disk.