This study highlights a gap in the exploration of how users perceive and emotionally respond to different robotic materials. Given that current research focuses primarily on functional and engineering aspects, this project seeks to address how material properties influence user interactions and perceptions. The project aims to analyze affective responses to various materials and explore potential roles for robots in domestic settings. By emphasizing the interplay between materiality and emotional engagement, this thesis contributes to a deeper understanding of how physical materials can resonate with the user on an intuitive and subconscious level. To visualize the findings derived from carefully selected qualitative methods, I have suggested a framework that deconstructs the elements of Role, Material, and Feeling, supporting the idea that interaction with robots occurs on a more profound level.