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Dynamics of anisotropic colloidal systems: What to choose, DLS, DDM or XPCS?
Malmö University, Faculty of Health and Society (HS), Department of Biomedical Science (BMV). Lund Univ, Dept Chem, Div Phys Chem, Lund, Sweden.ORCID iD: 0000-0001-5585-2065
Univ Milan, Dept Med Biotechnol & Translat Med, Milan, Italy.ORCID iD: 0000-0001-5470-3017
ESRF European Synchrotron, Grenoble, France; Diamond Light Source Ltd, Didcot, England.ORCID iD: 0000-0001-8502-544X
ESRF European Synchrotron, Grenoble, France.ORCID iD: 0000-0003-1957-1041
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2024 (English)In: Journal of Colloid and Interface Science, ISSN 0021-9797, E-ISSN 1095-7103, Vol. 660, p. 314-320Article in journal (Refereed) Published
Abstract [en]

Investigation of the dynamics of colloids in bulk can be hindered by issues such as multiple scattering and sample opacity. These challenges are exacerbated when dealing with inorganic materials. In this study, we employed a model system of Akaganeite colloidal rods to assess three leading dynamics measurement techniques: 3D -(depolarized) dynamic light scattering (3D-(D)DLS), polarized -differential dynamic microscopy (P-DDM), and x-ray photon correlation spectroscopy (XPCS). Our analysis revealed that the translational and rotational diffusion coefficients captured by these methods show a remarkable alignment. Additionally, by examining the q -ranges and maximum volume fractions for each approach, we offer insights into the best technique for investigating the dynamics of anisotropic systems at the colloidal scale.

Place, publisher, year, edition, pages
Elsevier, 2024. Vol. 660, p. 314-320
National Category
Physical Chemistry
Identifiers
URN: urn:nbn:se:mau:diva-66482DOI: 10.1016/j.jcis.2023.12.163ISI: 001167603400001PubMedID: 38244498Scopus ID: 2-s2.0-85182733574OAI: oai:DiVA.org:mau-66482DiVA, id: diva2:1847003
Available from: 2024-03-26 Created: 2024-03-26 Last updated: 2024-12-02Bibliographically approved

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Kamal, Mohammad Arif

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Kamal, Mohammad ArifBrizioli, MatteoZinn, ThomasNarayanan, TheyencheriGiavazzi, Fabio
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