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Interfacial Fluid Rheology of Soft Particles
Rhein Westfal TH Aachen, Inst Phys Chem, Landoltweg 2, D-52074 Aachen, Germany..
Wageningen Univ & Res, Lab Phys Chem & Soft Matter, Stippeneng 4, NL-6708 WE Wageningen, Netherlands..
Rhein Westfal TH Aachen, Inst Phys Chem, Landoltweg 2, D-52074 Aachen, Germany..
Univ Utrecht, Debye Inst Nanomat Sci, Soft Condensed Matter Biophys, Princetonplein 1, NL-3584 CC Utrecht, Netherlands..ORCID iD: 0000-0003-2468-9351
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2023 (English)In: Physical Review Letters, ISSN 0031-9007, E-ISSN 1079-7114, Vol. 131, no 25, article id 258202Article in journal (Refereed) Published
Abstract [en]

In situ interfacial rheology and numerical simulations are used to investigate microgel monolayers in a wide range of packing fractions, xi(2D). The heterogeneous particle compressibility determines two flow regimes characterized by distinct master curves. To mimic the microgel architecture and reproduce experiments, an interaction potential combining a soft shoulder with the Hertzian model is introduced. In contrast to bulk conditions, the elastic moduli vary nonmonotonically with xi(2D) at the interface, confirming long-sought predictions of reentrant behavior for Hertzian-like systems.

Place, publisher, year, edition, pages
American Physical Society, 2023. Vol. 131, no 25, article id 258202
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Physical Chemistry
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URN: urn:nbn:se:mau:diva-66158DOI: 10.1103/PhysRevLett.131.258202ISI: 001153469900006PubMedID: 38181345Scopus ID: 2-s2.0-85180937470OAI: oai:DiVA.org:mau-66158DiVA, id: diva2:1841070
Available from: 2024-02-27 Created: 2024-02-27 Last updated: 2024-02-27Bibliographically approved

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Scotti, Andrea

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