Laser-induced-fluorescence lifetime measurements and relativistic Hartree-Fock oscillator strength calculations in singly ionized platinumShow others and affiliations
2008 (English)In: Physical Review A. Atomic, Molecular, and Optical Physics, ISSN 1050-2947, E-ISSN 1094-1622, Vol. 77, no 2, article id 022501Article in journal (Refereed) Published
Abstract [en]
Radiative lifetimes of eight odd-parity states of Pt II, in the energy range from 51 408 to 64 388 cm−1, have been measured by means of the time-resolved laser-induced-fluorescence technique. Free, singly ionized platinum ions were obtained in a laser-produced plasma and a tunable laser with 1.5 ns duration pulse was used to selectively excite the Pt+ ions. The comparison of the experimental results with relativistic Hartree-Fock calculations emphasizes the importance of valence-valence correlation and of core-polarization effects in this complex ion. A new and extensive set of calculated oscillator strengths and transition probabilities is reported in the present paper.
Place, publisher, year, edition, pages
American Physical Society, 2008. Vol. 77, no 2, article id 022501
National Category
Atom and Molecular Physics and Optics
Identifiers
URN: urn:nbn:se:mau:diva-63258DOI: 10.1103/physreva.77.022501ISI: 000253763900056Scopus ID: 2-s2.0-38949211533OAI: oai:DiVA.org:mau-63258DiVA, id: diva2:1807678
2023-10-272023-10-272023-10-27Bibliographically approved