Investigation of catalytic hydrogen sensors with platinum group catalystsShow others and affiliations
2021 (English)In: Sensors and actuators. B, Chemical, ISSN 0925-4005, E-ISSN 1873-3077, Vol. 346, article id 130515Article in journal (Refereed) Published
Abstract [en]
Environmental deterioration and limited resources of hydrocarbons push the development of alternative power sources. One of the most promising energy carriers is hydrogen. However, handling hydrogen is more hazardous than the use of hydrocarbons because it has a significantly wider flammable range. Thus the development of new sensors for preventing hydrogen leakage is the actual task of modern materials science and chemical engineering. In this work, the response of catalytic sensors to hydrogen with different catalysts of platinum group (Pt, Pd, Ir, Rh, Pt + Pd, Pt + Pd + Rh, Pt + Pd + Ir) in the pre-explosion concentration range is studied. Temperature dependencies of sensitivity are discussed. A hysteresis in sensor response is observed during the cycling of the supply voltage. This phenomenon can be explained by partial transformation of platinum group metal oxides into metallic phase at a temperature of more than 500 °C and reverse metal oxidation at temperatures less than 400 °C. It has been shown that the sensors with catalysts containing Ir and Rh demonstrate more preferable characteristics for practical applications. © 2021 Elsevier B.V.
Place, publisher, year, edition, pages
Elsevier, 2021. Vol. 346, article id 130515
Keywords [en]
Catalytic sensor, Hydrogen, Platinum group catalyst, Sensitivity, Catalysts, Deterioration, Hydrocarbons, Platinum compounds, Alternative power, Energy carriers, Environmental deterioration, Hydrogen leakage, Hydrogen sensor, Platinum-group, Power sources, ]+ catalyst
National Category
Other Environmental Engineering
Identifiers
URN: urn:nbn:se:mau:diva-45058DOI: 10.1016/j.snb.2021.130515ISI: 000692026900006Scopus ID: 2-s2.0-85111596415OAI: oai:DiVA.org:mau-45058DiVA, id: diva2:1587024
2021-08-232021-08-232023-10-03Bibliographically approved