Better understanding of the formation and distribution of hydrides, elastic and plastic strains in deformed polycrystalline, multiphase materials such as digitally manufactured Ti-6Al-4V is important for structural engineering. Polycrystalline Ti-6Al4V alloy samples produced by additive manufacturing techniques called electron beam melting (EBM) have been studied at third generation, high energy synchrotron X-Ray diffraction beam line with energy dispersive X-Ray diffraction setup. The elastic strain in the as built and hydrogenated material determined by extracting unit cell parameters of the existing phases in the system by using whole pattern analysis method Rietveld and Pawley.